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1

A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst

Michael G. Organ, Stephanie Avola, Igor Dubovyk, Niloufar Hadei, Eric Assen B. Kantchev, Christopher J. O'Brien, Cory Valente

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 253 KB

english, 2006

2

Computational and experimental comparison of diphosphane and diene ligands in the Rh-catalysed carboxylation of organoboron compounds with CO2

Qin, Hua-Li, Han, Jia-Bin, Hao, Jian-Hong, Kantchev, Eric Assen B.

Journal:

Green Chemistry

Year:

2014

Language:

english

File:

PDF, 2.22 MB

english, 2014

3

Membrane interaction and structure of the transmembrane domain of influenza hemagglutinin and its fusion peptide complex

Ding-Kwo Chang, Shu-Fang Cheng, Eric Aseen B Kantchev, Chi-Hui Lin, Yu-Tsan Liu

Journal:

Year:

2008

Language:

english

File:

PDF, 1.43 MB

english, 2008

4

Oligosaccharide synthesis on a soluble, hyperbranched polymer support via thioglycoside activation

Eric Assen B. Kantchev, Scott J. Bader, Jon R. Parquette

Journal:

Year:

2005

Language:

english

File:

PDF, 529 KB

english, 2005

5

N-heterocycle carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: a highly active, practical and versatile catalyst for the Heck–Mizoroki reaction

Peh, Guang-Rong, Kantchev, Eric Assen B., Zhang, Chi, Ying, Jackie Y.

Journal:

Organic & Biomolecular Chemistry

Year:

2009

Language:

english

File:

PDF, 582 KB

english, 2009

6

Solvent and base in one: Tetra-n-butylammonium acetate as a multi-purpose ionic liquid medium for the Ru-catalysed directed mono- and di-o-C-H arylation reactions

Kantchev, Eric A. B., Zou, Ya-Ling, Wang, Zhen-Yu, Feng, Yin-Mao, Li, You-Gui

Journal:

European Journal of Organic Chemistry

Year:

2017

Language:

english

File:

PDF, 1.95 MB

english, 2017

7

DFT modelling of a diphosphane − N-heterocyclic carbene-Rh(I) pincer complex rearrangement: A computational evaluation of the electronic effects in C-P bond activation

Qin, Hua-Li, Leng, Jing, Zhang, Wenqin, Kantchev, Eric Assen Bonev A B

Journal:

Dalton Transactions

Year:

2018

Language:

english

File:

PDF, 1.27 MB

english, 2018

8

ChemInform Abstract: Rational Exploration of N-Heterocyclic Carbene (NHC) Palladacycle Diversity: A Highly Active and Versatile Precatalyst for Suzuki—Miyaura Coupling Reactions of Deactivated Aryl and Alkyl Substrates.

Guang-Rong Peh, Eric Assen B. Kantchev, Jun-Cheng Er, Jackie Y. Ying

Journal:

Year:

2010

File:

PDF, 32 KB

2010

9

Secondary structure, phospholipid membrane interactions, and fusion activity of two glutamate-rich analogs of influenza hemagglutinin fusion peptide

Eric Assen B. Kantchev, Shu-Fang Cheng, Cheng-Wei Wu, Hung-Jen Huang, Ding-Kwo Chang

Journal:

Archives of Biochemistry and Biophysics

Year:

2004

Language:

english

File:

PDF, 350 KB

english, 2004

10

ChemInform Abstract: Ruthenium-Catalyzed Direct Arylations with Aryl Chlorides

Zha, Gao-Feng, Qin, Hua-Li, Kantchev, Eric Assen B.

Journal:

Year:

2016

File:

PDF, 16 KB

2016

11

Bulky Phosphane Ligand for Monoselective Ruthenium-Catalyzed, Directed o-C–H Arylation with Challenging Aryl Chlorides

Li, You-Gui, Wang, Zhen-Yu, Zou, Ya-Ling, So, Chau-Ming, Kwong, Fuk-Yee, Qin, Hua-Li, Kantchev, Eric

Journal:

Year:

2016

Language:

english

File:

PDF, 200 KB

english, 2016

12

Direct Fmoc/tert-Bu solid phase synthesis of octamannosyl polylysine dendrimer–peptide conjugates

Eric Assen B. Kantchev, Chung-Chieh Chang, Ding-Kwo Chang

Journal:

Year:

2006

Language:

english

File:

PDF, 322 KB

english, 2006

13

Chemically accurate and computationally-efficient time-dependent density functional theory (TDDFT) modeling of the UV/Vis spectra of Pechmann dyes and related compounds

Eric Assen B. Kantchev, Tyler B. Norsten, Michael B. Sullivan

Journal:

Procedia Computer Science

Year:

2011

File:

PDF, 1.03 MB

2011

14

Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis

Sasaki, Keigo, Nishimura, Takahiro, Shintani, Ryo, Kantchev, Eric Assen B., Hayashi, Tamio

Journal:

Chemical Science

Year:

2012

Language:

english

File:

PDF, 735 KB

english, 2012

15

Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction

Christopher J. O'Brien, Eric Assen B. Kantchev, Cory Valente, Niloufar Hadei, Gregory A. Chass, Alan Lough, Alan C. Hopkinson, Michael G. Organ

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 208 KB

english, 2006

16

Time-dependent density functional theory (TDDFT) modelling of Pechmann dyes: from accurate absorption maximum prediction to virtual dye screening

Kantchev, Eric Assen B., Norsten, Tyler B., Sullivan, Michael B.

Journal:

Organic & Biomolecular Chemistry

Year:

2012

Language:

english

File:

PDF, 1.15 MB

english, 2012

17

Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study

Kantchev, Eric Assen B.

Journal:

Chemical Science

Year:

2013

Language:

english

File:

PDF, 1.48 MB

english, 2013

18

Pd-Catalyzed Aryl Amination Mediated by Well Defined, N-Heterocyclic Carbene (NHC)–Pd Precatalysts, PEPPSI

Michael G. Organ, Mirvat Abdel-Hadi, Stephanie Avola, Igor Dubovyk, Niloufar Hadei, Eric Assen B. Kantchev, Christopher J. O'Brien, Mahmoud Sayah, Cory Valente

Journal:

Chemistry - A European Journal

Year:

2008

Language:

english

File:

PDF, 395 KB

english, 2008

19

Catalyst-Counterion Controlled, Regioselective C–C Bond Cleavage in 1-Azabiphenylene: Synthesis of Selectively Substituted Benzoisoquinolines

Frejka, David, Ulč, Jan, Kantchev, Eric Assen B., Císařová, Ivana, Kotora, Martin

Journal:

Year:

2018

Language:

english

File:

PDF, 1.06 MB

english, 2018

20

Electronic Nature of N-Heterocyclic Carbene Ligands: Effect on the Suzuki Reaction

Hadei, Niloufar, Kantchev, Eric Assen B., O'Brie, Christopher J., Organ, Michael G.

Journal:

Organic Letters

Year:

2005

Language:

english

File:

PDF, 73 KB

english, 2005

21

Tunable, dynamic and electrically stimulated lectin–carbohydrate recognition on a glycan-grafted conjugated polymer

Luo, Shyh-Chyang, Kantchev, Eric Assen B., Zhu, Bo, Siang, Yuen Wee, Yu, Hsiao-hua

Journal:

Chemical Communications

Year:

2012

Language:

english

File:

PDF, 1.31 MB

english, 2012

22

The origin of regio- and enantioselectivity in the Rh/chiral 1,4-diene-catalyzed addition of phenylboronic acid to enones: insights from DFT

Kantchev, Eric Assen B.

Journal:

Chemical Communications

Year:

2011

Language:

english

File:

PDF, 960 KB

english, 2011

23

A Bulky Disulfoxide Ligand for Pd-Catalyzed Oxidative Allylic C–H Amination with 2,2,2-Trichloroethyl Tosyl Carbamate

Li, You-Gui, Li, Li, Yang, Ming-Yue, He, Gang, Kantchev, Eric Assen B.

Journal:

Journal of Organic Chemistry

Year:

2017

Language:

english

File:

PDF, 570 KB

english, 2017

24

DFT computations support the σ-complex assisted metathesis (σ-CAM) mechanism for the 1,4-Rh shift of Cp*Rh( iii )–(η 1 -β-styryl) complexes

Li, Yougui, He, Gang, Kantchev, Eric Assen B.

Journal:

Physical Chemistry Chemical Physics

Year:

2014

Language:

english

File:

PDF, 2.03 MB

english, 2014

25

Encyclopedia of Reagents for Organic Synthesis || trans -[1,3-(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride (PEPPSI ™ -IPr)

Kantchev, Eric Assen B.

Year:

2001

Language:

english

File:

PDF, 85 KB

english, 2001

26

Thiophene-Containing Pechmann Dye Derivatives

Norsten, Tyler B., Kantchev, Eric Assen B., Sullivan, Michael B.

Journal:

Organic Letters

Year:

2010

Language:

english

File:

PDF, 1.20 MB

english, 2010

27

Conductivity Shift of Polyethylenedioxythiophenes in Aqueous Solutions from Side-Chain Charge Perturbation

Ali, Emril Mohamed, Kantchev, Eric Assen B., Yu, Hsiao-hua, Ying, Jackie Y.

Journal:

Year:

2007

Language:

english

File:

PDF, 67 KB

english, 2007

28

The Challenge of Linear ( E )-Enones in the Rh-Catalyzed, Asymmetric 1,4-Addition Reaction of Phenylboronic Acid: A DFT Computational Analysis

Qin, Hua-Li, Chen, Xiao-Qing, Shang, Zhen-Peng, Kantchev, Eric Assen B.

Journal:

Chemistry - A European Journal

Year:

2015

Language:

english

File:

PDF, 1.39 MB

english, 2015

29

Hyperbranched Polyester Supported Disaccharide Synthesis: The Effect of Loading Level on Glycosylation Efficiency

Kantchev, Eric Assen, Parquette*, Jon R.

Journal:

Year:

2005

Language:

english

File:

PDF, 125 KB

english, 2005

30

Palladium Complexes of N-Heterocyclic Carbenes as Catalysts for Cross-Coupling Reactions—A Synthetic Chemist's Perspective

Eric Assen B. Kantchev, Christopher J. O'Brien, Michael G. Organ

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 5.29 MB

english, 2007

31

Computational modelling of the enantioselectivity in the asymmetric 1,4-addition reaction catalyzed by a Rh complex of a S-chiral disulfoxide

Li, You-Gui, Li, Li, Yang, Ming-Yue, Qin, Hua-Li, Kantchev, Eric Assen B.

Journal:

Year:

2015

Language:

english

File:

PDF, 1.05 MB

english, 2015

32

Ruthenium-catalyzed direct arylations with aryl chlorides

Zha, Gao feng, Qin, Hual-Li, Kantchev, Eric A B

Journal:

Year:

2016

Language:

english

File:

PDF, 947 KB

english, 2016

33

Computational Investigation of the 1,4-Rh Shift in the [(Ph 2 PCH 2 CH 2 PPh 2 )Rh]-Catalyzed Alkyne Arylation Reaction

Kantchev, Eric Assen B., Zhou, Feng, Pangestu, Surya R., Sullivan, Michael B., Su, Haibin

Journal:

European Journal of Organic Chemistry

Year:

2015

Language:

english

File:

PDF, 2.97 MB

english, 2015

34

Structure–Activity Relationship Analysis of Pd–PEPPSI Complexes in Cross-Couplings: A Close Inspection of the Catalytic Cycle and the Precatalyst Activation Model

Joanna Nasielski, Dr. Nilofaur Hadei, George Achonduh, Dr. Eric Assen B. Kantchev, Dr. Christopher J. O'Brien, Alan Lough, Prof. Michael G. Organ

Journal:

Chemistry - A European Journal

Year:

2010

Language:

english

File:

PDF, 559 KB

english, 2010

35

A First-Principles Examination of the Asymmetric Induction Model in the Binap/Rh I -Catalysed 1,4-Addition of Phenylboronic Acid to Cyclic Enones by Density Functional Theory Calculations

Qin, Hua-Li, Chen, Xiao-Qing, Huang, Yi-Zhen, Kantchev, Eric Assen B.

Journal:

Chemistry - A European Journal

Year:

2014

Language:

english

File:

PDF, 487 KB

english, 2014

36

The First Negishi Cross-Coupling Reaction of Two Alkyl Centers Utilizing a Pd—N-Heterocyclic Carbene (NHC) Catalyst.

Niloufar Hadei, Eric Assen B. Kantchev, Christopher J. O'Brien, Michael G. Organ

Journal:

Year:

2005

File:

PDF, 25 KB

2005

37

O , O′ -Disubstituted N , N′ -Dihydroxynaphthalenediimides (DHNDI): First Principles Designed Organic Building Blocks for Materials Science

Kantchev, Eric Assen B., Tan, Huei Shuan, Norsten, Tyler B., Sullivan, Michael B.

Journal:

Organic Letters

Year:

2011

Language:

english

File:

PDF, 2.23 MB

english, 2011

38

First Principles (DFT) Characterization of Rh I /dppp-Catalyzed CH Activation by Tandem 1,2-Addition/1,4-Rh Shift Reactions of Norbornene to Phenylboronic Acid

Kantchev , Eric Assen B., Pangestu, Surya R., Zhou, Feng, Sullivan, Michael B., Su, Hai-Bin

Journal:

Chemistry - A European Journal

Year:

2014

Language:

english

File:

PDF, 1.42 MB

english, 2014

39

Computational modelling of the enantioselectivity in the asymmetric 1,4-addition of phenylboronic acid to a bulky, doubly pro-chiral maleimide catalyzed by a Rh/chiral diene complex

Kantchev, Eric A B, Qin, Hua-Li, Shang, Zhen-peng, Zhu, Kaicheng, Li, Yougui

Journal:

Year:

2015

Language:

english

File:

PDF, 1.19 MB

english, 2015

40

Ruthenium-Catalyzed Oxidative Formal Aza-Diels−Alder Reactions: Enantioselective Synthesis of Benzo[a]quinolizine-2-ones

Yao, Yuan, Zhu, Hai-Jie, Li, Fang, Zhu, Cheng-Feng, Luo, Yun-Fei, Wu, Xiang, Kantchev, Eric

Journal:

Advanced Synthesis & Catalysis

Year:

2017

Language:

english

File:

PDF, 1.98 MB

english, 2017

41

Cover Picture: Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction / A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst (Chem. Eur. J. 18/2006)

Christopher J. O'Brien, Eric Assen B. Kantchev, Cory Valente, Niloufar Hadei, Gregory A. Chass, Alan Lough, Alan C. Hopkinson, Michael G. Organ, Stephanie Avola, Igor Dubovyk

Journal:

Chemistry - A European Journal

Year:

2006

Language:

english

File:

PDF, 380 KB

english, 2006

42

Copper-Catalyzed Regioselective 1,2-Alkylesterification of Dienes to Allylic Esters

Li, Yougui, Han, Yulong, Xiong, Haigen, Zhu, Nengbo, Qian, Bo, Ye, Changqing, Kantchev, Eric Assen B., Bao, Hongli

Journal:

Organic Letters

Year:

2016

Language:

english

File:

PDF, 833 KB

english, 2016

43

Cooperativity of axial and centre chirality in the biaryl disulfoxide/Rh( i )-catalysed asymmetric 1,4-addition of arylboronic aids to 2-cyclohexenone: a DFT study

Zha, Gao-Feng, Qin, Hua-Li, Kantchev, Eric Assen B.

Journal:

Organic & Biomolecular Chemistry

Year:

2017

Language:

english

File:

PDF, 721 KB

english, 2017

44

Thiophene-Containing Pechmann Dyes and Related Compounds: Synthesis, and Experimental and DFT Characterisation

Dr. Eric Assen B. Kantchev, Dr. Tyler B. Norsten, Marilyn L. Y. Tan, Joey J. Y. Ng, Dr. Michael B. Sullivan

Journal:

Chemistry - A European Journal

Year:

2012

Language:

english

File:

PDF, 1.54 MB

english, 2012

45

Density Functional Theory Investigation of the Alkyl–Alkyl Negishi Cross-Coupling Reaction Catalyzed by N-Heterocyclic Carbene (NHC)–Pd Complexes

Gregory A. Chass, Christopher J. O'Brien, Niloufar Hadei, Eric Assen B. Kantchev, Wei-Hua Mu, De-Cai Fang, Alan C. Hopkinson, Imre G. Csizmadia, Michael G. Organ

Journal:

Chemistry - A European Journal

Year:

2009

Language:

english

File:

PDF, 1.24 MB

english, 2009

46

Direct solid-phase synthesis and fluorescence labeling of large, monodisperse mannosylated dendrons in a peptide synthesizer

Kantchev, Eric Assen B., Chang, Chung-Chieh, Cheng, Shu-Fang, Roche, Annie-Claude, Chang, Ding-Kwo

Journal:

Organic & Biomolecular Chemistry

Year:

2008

Language:

english

File:

PDF, 430 KB

english, 2008

47

ChemInform Abstract: Copper-Catalyzed Regioselective 1,2-Alkylesterification of Dienes to Allylic Esters.

Li, Yougui, Han, Yulong, Xiong, Haigen, Zhu, Nengbo, Qian, Bo, Ye, Changqing, Kantchev, Eric Assen B., Bao, Hongli

Journal:

Year:

2016

File:

PDF, 24 KB

2016

48

First principles (DFT) characterization of the Rh(I)/dppe-catalyzed ring expansion of 2-alkylbenzocyclobutenones.

Kantchev, Eric A. B., Qin, Hua-Li, Zhao, Chuang, Leng, Jing

Journal:

Chemistry - A European Journal

Year:

2017

Language:

english

File:

PDF, 1.85 MB

english, 2017

49

Aus der Sicht des Synthetikers: Palladiumkomplexe N-heterocyclischer Carbene als Katalysatoren für Kreuzkupplungen

Eric Assen B. Kantchev, Christopher J. O'Brien, Michael G. Organ

Journal:

Angewandte Chemie

Year:

2007

Language:

german

File:

PDF, 5.54 MB

german, 2007

50

Room-Temperature Negishi Cross-Coupling of Unactivated Alkyl Bromides with Alkyl Organozinc Reagents Utilizing a Pd/ N -Heterocyclic Carbene Catalyst

Hadei, Niloufar, Kantchev, Eric Assen B., O'Brie, Christopher J., Organ, Michael G.

Journal:

Journal of Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 141 KB

english, 2005

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